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21.
Phu H. Dang Linh T. T. Nguyen Hue T. T. Nguyen Tho H. Le Truong N. V. Do Hai X. Nguyen 《Natural product research》2019,33(20):2883-2889
From an EtOAc-soluble fraction of the stem barks of Swintonia floribunda (Anacardiaceae), one new dimeric alkylresorcinol named integracin E (1), together with 4 known compounds (2–5) were isolated. Their chemical structures were elucidated based on the spectroscopic data interpretation. The absolute configuration of 1 was determined by the specific rotation analysis of its acid-catalyzed hydrolysis product. Compound 1 showed potent tyrosinase inhibitory activity with an IC50 value of 48.2?μM. 相似文献
22.
We experimentally analyze the heat capacity and thermal expansion of reference solids in a wide temperature range from several Kelvin to melting temperature,and establish a universal double-linear relation between the experimental heat capacity Cp and thermal expansion β,which is different from the previous models.The universal behavior between heat capacity and thermal expansion is important to predict the thermodynamic parameters at constant pressure,and is helpful for understanding the nature of thermal properties in solids. 相似文献
23.
Acta Mathematicae Applicatae Sinica, English Series - This paper proposes a method for modelling volatilities (conditional covariance matrices) of high dimensional dynamic data. We combine the... 相似文献
24.
In the last decade,the functionally graded carbon nanotube reinforced composites(FG-CNTRCs)have attracted considerable interest due to their excellent mechanical properties,and the structures made of FG-CNTRCs have found broad potential applications in aerospace,civil and ocean engineering,automotive industry,and smart structures.Here we review the literature regarding the mechanical analysis of bulk CNTR nanocomposites and FG-CNTRC structures,aiming to provide a clear picture of the mechanical modeling and properties of FG-CNTRCs as well as their composite structures.The review is organized as follows:(1)a brief introduction to the functionally graded materials(FGM),CNTRCs and FG-CNTRCs;(2)a literature review of the mechanical modeling methodologies and properties of bulk CNTRCs;(3)a detailed discussion on the mechanical behaviors of FG-CNTRCs;and(4)conclusions together with a suggestion of future research trends. 相似文献
25.
Zhang Qun-Zheng Li Zhi-Yuan Zhang Le Lv Na Pan Qing Ke Cong-Yu Zhang Xun-Li 《Russian Journal of Organic Chemistry》2020,56(12):2201-2206
Russian Journal of Organic Chemistry - There remain challenges for effectively synthesizing heterocycles containing both piperidine and pyridine rings, mainly due to the inefficient synthetic... 相似文献
26.
The contents of topological classification of matter are enriched by non-Hermiticity, such as exceptional points, bulk-edge correspondence, and skin effects. Physically, gain and loss can be introduced by imaginary on-site potentials of lattice Hamiltonians, and the topological phase transition for a cross-linked chain in the presence of such non-Hermiticity is investigated. The topological phase diagram in terms of a winding number is obtained analytically with phase boundaries coinciding with the surfaces of exceptional points. The topologically original edge states with distribution mainly at the joints between domains of different phases are protected even for long chains. The non-Hermitian topological feature can also be reflected by vortex structures in the vector fields of complex eigenenergies, expected values of Pauli matrices, and trajectories of these quantities. This model may be implemented in coupled photonic crystals, fermions trapped in optical lattice, or non-Hermitian electrical-circuit lattices, and the edge states are immune to various kinds of disorders until topological phase transition occurs. This work gives insight into the influence of non-Hermiticity on topological phase of matter. 相似文献
27.
Lens-less Fourier-transform holography has been actively studied because of its simple optical structure and its single-shot recording.However,a low-contrast interferogram between the reference and object waves limits its signal to noise ratio.Here,multi-reference lens-less Fourier-transform holography with a Greek-ladder sieve array is proposed in the experiment and demonstrated effectively to improve the signal to noise ratio.The key technique in our proposed method is a Greek-ladder sieve array,which acts as not only a wave-front modulator but also a beam splitter.With advantages of the common path,single shot,and no need for a lens,this system has enormous potential in imaging and especially in extreme ultraviolet and soft X-ray holography. 相似文献
28.
A Supramolecular Chiral Auxiliary Approach: “Remote Control” of Stereochemistry at a Hierarchically Assembled Dimeric Helicate 下载免费PDF全文
David Van Craen Prof. Dr. Markus Albrecht Prof. Dr. Gerhard Raabe Fangfang Pan Prof. Dr. Kari Rissanen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(10):3255-3258
Dimeric hierarchically‐assembled titanium(IV) helicates are in solvent‐dependent equilibrium with the corresponding monomers. Statistically formed mixtures of such complexes bearing chiral stereocontrolling ligands and achiral diene‐substituted ligands show high diastereoselectivity and reasonable enantioselectivity in the Diels–Alder reaction with maleimides if the reaction proceeds with the dimer but not with the monomer. Thus, solvent dependent switching between the monomer and dimer enables on/off switching of the enantioselectivity. 相似文献
29.
Molecular dynamics simulation of DNA‐directed assembly of nanoparticle superlattices using patterned templates 下载免费PDF全文
S. Pan T. I. N. G. Li M. Olvera de la Cruz 《Journal of Polymer Science.Polymer Physics》2016,54(17):1687-1692
DNA‐directed assembly is a well developed approach in constructing desired nano‐architectures. On the other hand, E‐beam lithography is widely utilized for high resolution nano‐scale patterning. Recently, a new technique combining these two methods was developed to epitaxially grow DNA‐mediated nanoparticle superlattices on patterned substrates. However, defects are observed in epitaxial layers which restricts this technique from building large‐scale superlattices for real applications. Here we use molecular dynamics simulations to study and predict defect formation on adsorbed superlattice monolayers. We demonstrate that this epitaxial growth is energetically driven by maximizing DNA hybridization between the epitaxial layer and the substrate and that the shape anisotropy of the DNA‐mediated template posts leads to structural defects. We also develop design rules to dramatically reduce defects on epitaxial layers. Ultimately, with the assist of the computational study, this technique will open the door to constructing well‐ordered, three‐dimensional novel nanomaterials. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1687–1692 相似文献
30.